Infrared Spectroscopy, Example #6


Analysis: C3H10NO
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C3710NO

From the molecular formula, the compound has "1 degree of unsaturation" (one double bond, carbonyl or ring).

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3400-3200 cm-1: strong peak suggesting OH or NH
3100 cm-1: minor peak indicating possible unsaturated CH
2900 cm-1: minor peaks indicating saturated CH
2200 cm-1: no unsymmetrical triple bonds
1650 cm-1: strong carbonyl absorbance
1550 cm-1: moderate absorbance band, characteristic of "N-H bending"

The spectrum seems to be consistent with a compound containing a carbonyl group and an N-H group. The low carbonyl band (1650 cm-1) and the N-H bending band strongly suggest an amide linkage; this pair of absorbances are often termed the "amide I and II" bands.

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Structure: structure

IUPAC Name: N-methylacetamide (N-methylethanamide)

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Copyright 1996, Paul R. Young, University of Illinois at Chicago, All Rights Reserved