CHEM 524 -- Outline (Part 7)
VI. C. Special Topics in optics
1. Modulation
a. Characteristics
(Figure 1): depth, duty cycle, shape, frequencyb. Styles
: Chopper, polarization, frequency modulation (grating dither), transient grating (nonlinear effect, crossed laser beams), Interference2. Polarizers
-- random in - linear out (E field with specific orientation)a. Aligned dipole transitions
-- vis & uv, absorbing (Polaroid, stretched film with dye)
-- IR: reflection:
wire (grid) made like a grating (narrow spacing l > 2d), Al on ridgesb. Reflecting
-- use Brewster angle (
stack of plates), each one loses some intensity from a specific polarization and transmits all of the other polarization-- use birefringence index total internal reflection (Glan Prism) one polarization is transmited with some reflection loss, the other totally reflected (narrow angle of acceptance),
Glan Taylor has air gap, narrow angle of acceptance, capable of high power-- beam split (Rochon, Wollaston etc.), transmit both, but divergent angle, if beam is collimated, can separate at a distance, MgF2 used in vac-uv as Rochon, LiIO4 sometimes as a
Wollaston3. Circular polarization
a. Wave plate
-- birefringence retardation
, d, depends on wavelength, l, the difference in refractive index, Dn = nx-ny and thickness, z, d = (2p/l) Dn z-- as light passes through crystal, shift phase of two orthogonally polarized beams (x,y), when recombine, if
l/4 shift (d = p/2) then circular (left or right), if d = p (or l/2) then perpendicular linear polarization resultsother values give elliptically polarized light--
Soliel-Babinet compensator will do this vaiably by sliding a wedge into the beam to vary zb.
Fresnel rhomb -- reflection retardation -- broad band circular polarizationc. Modulator:
-- Electrooptic induce birefringence with voltage polarization (e.g. KDP typical, Pockels Cell)
-- Photoelastic
periodic stress induce birefringence any isotropic material acoustically matched to driver can be basis, wide spectra region possible, periodic retardation, variable amplitude or wavelength of l/4 (right to left circular) or l/2 (parallel to perpendicular linear) retardationd. Faraday rotator
magnetic field rotate linear (not circ.) polarization to new orientation