Chem 524 Lecture notes (Sect. 6)
Interferometers
A. Fabry-Perot (text: Sect. 3-7, Figure 3-56)
multiple passes between partially reflecting surfaces
if paths differ by m l
if beam enters at angle lead to "fringes"
as spacing changes
l free spectral range:
sharpness of interference
depends on reflectivity (coefficient of finesse)
use: couple to monochromator etalon in laser select mode narrowline
B.
r/(1-r)2
CF = 4
à
enhance resolution to
encode frequency (wave number) by position interference at beam splitter on recombining from moving and fixed mirrors
creates signal
interpret by Fourier transform of intensity (response) vs.
1. Monochromatic light interferogram is sine wave
retardation measure path difference waves: constant move mirror at modulates signal: spectral response (F.T.): if this restricts resolution of
xm
2. Polychromatic light: interference between wave different frequency leads to envelope on interferogram oscillation reflect spectrum
Two frequenciesget beat pattern
Broader, must integrate over all contributions, envelop decays:
low Dx à
broad base line, high Dx
à interference of close frequencies
Finite motion of mirror limit resolution, bandshape
resolution ideal:
-- if D n too
small, then no interference
apodization
modify bandshape by convolving D(x), apold. Fct., reslti in lower resolution
but cleaner line shape
boxcar (no alternation), triangular (ramp), others (or more continuous variants)
3. FT Advantages
Jacquinot no slit throughout enhanced, but small aperture
high res
Fellgett multiplex all frequencies simultaneously detected
Connes frequency accuracy (compare/correct spectra)
Costs: lost 1/2 light back to source at Beam splitter
lack modulation depth (at large Dx values)only can transform modulation
phase errors need correction/distort bandshape
4. Phase correction
Digital spectra can miss Electronic frequency response Result Correct complex FT derive Re [~cos
)
"chirp"--lose symmetry at x=0
) has derivative shapes
Mertz algorithm measure over small
)
5. Alignment error and Aperture lower resolution
solid angle accepted: W = 2pa2 = 2pDn/n
divergence causes
loss modulation at large Dx
(loss resolution like apodize)
loss of frequency accuracy
mirror align cause
loss intensity, resolution high
(favor IR), rooftop
or corner cube can reduce
6. Indirect measure need F.T. computer must be fast, accurate co-add
7. Survey of Drive systems (handouts) older: 3-interferometer system (IR, White, laser), modern: 60deg B/S, Genzel interferometer (vacuum), FT-Raman setup