CHEM 524 Course Outline (Sect. 4)

III. Optics — Control of light — move it from source to detector through experiment

A. Lenses + Mirror (Text: Ch 3 & 1,4) design — shape & materials — efficiency

1.Basic concepts: index of refraction — n = c/v, c = 3 x 108m/s,

nglass ~ 1.5, nCaF2 ~ 1.35, nGe ~ 4

conservation law: r(l) + a(l) + T(l) = 1 - mirror T~ 0 & lens T ~ 1

dispersion (n increase with dec l) — dn(l)/dl < 0

Snell’s law of refraction: n, sin q1 = n2 sin q2,

reflection: q1 = q3 vs. refraction: q2 < q1 for n1 < n2

reflection loss: r(l) = (n2-n1/n2+n1)2, normal,

Brewster angle, — zero reflection loss in one polarization (II refl. plane) at specific angle qB = tan-1(n2/n1)

Total internal reflection, - n1>n2, r(l) max at q1=qc, qc = sin-1(n2/n1)

air — glass, eq goes here

2. Mirrors: spherical mirror imaging — reflection,

materials — Al(uv), Au(IR), coating can help r

2/R = 1/ S1 +1/ S2 =1/f,

S1 — object — O, S2 — image — I, R — radius (R<0 concave), f — focus

magnification: m = -I/0 = - S2/ S1

S1 > R — demagnify, f < S1 < R — magnify, S1 < f — no image

variations: plane, convex, aspherical

3. Lens: refraction straight line design, must transmit but losses due reflection or absorption

spectral region, material depenent:

Thin-lens

1/ S1 +1/ S2 =1/f,

operative formula

1/ S1 +1/ S2 =1/f,

AR coating — reduce reflection loss (n — index lens, n Å 1 air) - r=(n-1/n+1)2

-- add l/4 layer of index n1 = n — zero refl.

-- multilayer (N)— get zeros at (N — 1) l’s

4. Light gather power — trade off: more light or smaller image

F-number: [F/n] = f/D, D = (4A/p)1/2

Called the speed — smaller is faster

Irradiance (goes as square): halve f/n, quadruple light

Varies as solid angle, W, E=Bs(p/4)/(F/n)2

5. Abberations: chromatic, spherical, coma, astigmatism

B. Special

1. Fiber optics — total internal reflection — limits acceptance angle

2. Beam Splitter — divides beam in space

3. Filters —-- interference — narrow -band or cut off: