CHEM 524 Course Outline (Sect. 4)
III. Optics Control of light move it from source to detector through experiment
A. Lenses + Mirror (Text: Ch 3 & 1,4) design shape & materials efficiency
1.Basic concepts: index of refraction n = c/v, c = 3 x 108m/s,
nglass ~ 1.5, nCaF2 ~ 1.35, nGe ~ 4
conservation law: r(l) + a(l) + T(l) = 1 - mirror T~ 0 & lens T ~ 1
dispersion (n increase with dec l) dn(l)/dl < 0
Snells law of refraction: n, sin q1 = n2 sin q2,
reflection: q1 = q3 vs. refraction: q2 < q1 for n1 < n2
reflection loss: r(l) = (n2-n1/n2+n1)2, normal,
Brewster angle, zero reflection loss in one polarization (II refl. plane) at specific angle qB = tan-1(n2/n1)
Total internal reflection, - n1>n2, r(l) max at q1=qc, qc = sin-1(n2/n1)
air glass, eq goes here
2. Mirrors: spherical mirror imaging reflection,
materials Al(uv), Au(IR), coating can help r
2/R = 1/ S1 +1/ S2 =1/f,
S1 object O, S2 image I, R radius (R<0 concave), f focus
magnification: m = -I/0 = - S2/ S1
S1 > R demagnify, f < S1 < R magnify, S1 < f no image
variations: plane, convex, aspherical
3. Lens: refraction straight line design, must transmit but losses due reflection or absorption
spectral region, material depenent:
1/ S1 +1/ S2 =1/f,
operative formula
1/ S1 +1/ S2 =1/f,
AR coating reduce reflection loss (n index lens, n Å 1 air) - r=(n-1/n+1)2
-- add l/4 layer of index n1 = n zero refl.
-- multilayer (N) get zeros at (N 1) ls
4. Light gather power trade off: more light or smaller image
F-number: [F/n] = f/D, D = (4A/p)1/2
Called the speed smaller is faster
Irradiance (goes as square): halve f/n, quadruple light
Varies as solid angle, W, E=Bs(p/4)/(F/n)2
5. Abberations: chromatic, spherical, coma, astigmatism
B. Special
1. Fiber optics total internal reflection limits acceptance angle
2. Beam Splitter divides beam in space
3. Filters -- interference narrow -band or cut off: